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Title Page |
2 |
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Preface |
7 |
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Contents |
10 |
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Chapter 1 Basic Principles of the Kinetic Theory |
15 |
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Introduction |
15 |
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Molecular Structure of a Gas |
21 |
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Basic Principles |
21 |
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The Maxwellian Distribution Function |
22 |
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Determination of the Characteristic Velocities |
26 |
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Molecular Flux |
28 |
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Elementary Theory of Transport Processes |
30 |
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Characteristic Dimensions |
34 |
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Potentials of Molecular Interactions |
35 |
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Brownian Motion |
37 |
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Dynamics of a Binary Collision |
40 |
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Conservation Laws |
40 |
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Asymptotic Post-Collisional Velocities |
42 |
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Asymptotic Velocities for Gas Mixtures |
43 |
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Scattering Angle ? |
44 |
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Differential Cross Section |
46 |
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Appendix |
49 |
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Chapter 2 The Boltzmann Equation |
50 |
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The Boltzmann Equation |
50 |
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The BBGKY Hierarchy |
55 |
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The Liouville Theorem |
55 |
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Equations of the BBGKY Hierarchy |
57 |
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The Boltzmann Equation |
60 |
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The Transfer Equation |
64 |
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Summational Invariants |
66 |
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Macroscopic Description |
69 |
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Moments of the Distribution Function |
69 |
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Balance Equations for the Moments |
71 |
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The Definition of Equilibrium |
72 |
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The Maxwellian Distribution Function |
72 |
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Equilibrium States |
73 |
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Entropy and Entropy Flux |
79 |
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The $H$-Theorem |
82 |
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Interactions of Gas Molecules with Solid Surfaces |
82 |
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Scattering Kernels |
84 |
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The $H$-Theorem |
89 |
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The Paradoxes of Loschmidt and Zermelo |
90 |
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The Many Faces of Entropy |
91 |
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Appendix |
92 |
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Chapter 3 The Chapman–Enskog Method |
94 |
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Thermodynamics of a Single Fluid |
94 |
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Simplified Version of the Chapman–Enskog Method |
96 |
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The Integral Equation |
96 |
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Solution of the Integral Equation |
99 |
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Constitutive Equations and Transport Coefficients |
102 |
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Formal Version of the Chapman–Enskog Method |
106 |
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The dimensionless Boltzmann Equation |
106 |
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The Integral Equations |
107 |
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The Second Approximation |
109 |
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Expansion of the Scalar Coefficients A and B |
111 |
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Transport Coefficients |
114 |
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The BGK Model |
117 |
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Appendix |
120 |
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Chapter 4 Moment Methods |
121 |
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Balance Equations |
121 |
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Grad’s Distribution Function |
122 |
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Grad’s Distribution from Entropy Maximization |
125 |
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Determination of the Non-convective Fluxes, Production Terms, Entropy Density and Entropy Flux |
126 |
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Field Equations |
129 |
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The Method of Maxwell and Ikenberry–Truesdell |
131 |
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Calculation of the Production Terms |
131 |
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The Maxwellian Iteration |
132 |
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The Chapman–Enskog–Grad Combined Method |
134 |
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Non-inertial Reference Frames |
137 |
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Objective Tensors |
137 |
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The Boltzmann Equation in Non-inertial Reference Frames |
140 |
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Frame Dependence of the Heat Flux Vector |
142 |
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Appendix |
144 |
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Chapter 5 Polyatomic Gases |
145 |
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Some Properties of Polyatomic Gases |
145 |
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Semi-classical Model |
147 |
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Boltzmann and Transfer Equations |
147 |
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Macroscopic Description |
150 |
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The Equilibrium Distribution Function |
152 |
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Equilibrium States |
154 |
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The Non-equilibrium Distribution Function |
155 |
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The Laws of Navier–Stokes and Fourier |
157 |
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A Limiting Case |
161 |
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Classical Model |
163 |
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Basic Fields |
163 |
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Boltzmann and Transfer Equations |
164 |
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Transport Coefficients |
167 |
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Rough Spherical Molecules |
168 |
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Dynamics of a Binary Collision |
169 |
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Transport Coefficients |
171 |
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Appendix |
175 |
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Chapter 6 Dense Gases |
177 |
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The Thermal Equation of State |
177 |
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The Van der Waals Equation |
177 |
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The Virial Equation of State |
181 |
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Enskog’s Dense Gas |
183 |
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The Enskog’s Equation |
183 |
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The Transfer Equation |
184 |
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Macroscopic Description |
185 |
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Determination of the Potential Contributions |
186 |
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Equilibrium Constitutive Equations |
188 |
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Determination of the Kinetic Contributions |
189 |
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The Laws of Navier–Stokes and Fourier |
191 |
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The Modified Enskog Equation |
192 |
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Chapter 7 Granular Gases |
197 |
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Dynamics of a Binary Collision |
197 |
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The Boltzmann Equation |
198 |
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Macroscopic Description of a Granular Gas |
199 |
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The Chapman–Enskog Method |
200 |
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Integral Equations |
200 |
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First Approximation f$^(0)$ |
202 |
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Second Approximation f$^(1)$ |
205 |
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Constitutive Equations for the Pressure Tensor and the Heat Flux Vector |
209 |
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Granular Gases of Rough Spherical Molecules |
211 |
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Chapter 8 Mixtures of Monatomic Gases |
215 |
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Boltzmann and Transfer Equations |
215 |
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Macroscopic Description |
216 |
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Thermodynamics of Fluid Mixtures |
220 |
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The Equilibrium Distribution Function |
222 |
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Equilibrium States |
225 |
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Grad’s Distribution Function |
227 |
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The Combined Chapman–Enskog–Grad Method |
229 |
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The Navier–Stokes Law |
230 |
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The Laws of Fick and Fourier |
231 |
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Matrices as Functions of the Collision Integrals |
235 |
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Binary Mixtures |
238 |
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Coefficients of Shear Viscosity and Thermal Conductivity |
238 |
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Coefficients of Diffusion and Thermal–Diffusion Ratio |
240 |
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Coefficients for Some Intermolecular Potentials |
241 |
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Appendix |
243 |
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Chapter 9 Chemically Reacting Gas Mixtures |
246 |
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Thermodynamics of Chemically Reacting Systems |
246 |
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Extent of Reaction and Affinity |
246 |
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Chemical Potentials |
248 |
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The Law of Mass Action |
249 |
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The Arrhenius Equation |
251 |
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Boltzmann Equations |
253 |
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Transfer and Balance Equations |
255 |
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Models for Differential Cross Sections |
260 |
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Equilibrium Distribution Function |
261 |
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Transport Coefficients for $H2 + Cl HCl + H$ |
263 |
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Chapman–Enskog Method |
263 |
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Transport Coefficients |
268 |
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Quaternary Mixture H2, Cl, HCl, H |
271 |
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Remarks on the Reactive Contributions to the Transport Coefficients |
278 |
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Trend to Equilibrium of $H2 + Cl HCl + H$ |
279 |
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Determination of the Production Terms |
279 |
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Constituents at Same Temperature |
281 |
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The $H$-Theorem and the Tendency to Equilibrium |
286 |
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Symmetric Reactions |
291 |
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The Influence of the Heat of Reaction on Slow Reactions |
292 |
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Chemical Reactions without Activation Energy |
298 |
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Remarks on the Geometry of the Collisions |
302 |
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Remarks on Inelastic Reactive Collisions |
304 |
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References |
308 |
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Index |
309 |
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