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The Chemistry of Heterocycles - Structures, Reactions, Synthesis, and Applications
von: Theophil Eicher, Siegfried Hauptmann, Andreas Speicher
Wiley-VCH, 2013
ISBN: 9783527669875
646 Seiten,
Download: 6500 KB
Format: PDF
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geeignet für:
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Typ: A (einfacher Zugriff)
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Inhaltsverzeichnis |
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The Chemistry of Heterocycles |
5 |
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Contents |
7 |
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Preface to the Third Edition |
11 |
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Abbreviations and Symbols |
13 |
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1 The Structure of Heterocyclic Compounds |
17 |
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Reference |
20 |
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2 Systematic Nomenclature of Heterocyclic Compounds |
21 |
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2.1 Hantzsch-Widman Nomenclature |
22 |
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2.2 Replacement Nomenclature |
27 |
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2.3 Examples of Systematic Nomenclature |
28 |
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2.4 Important Heterocyclic Systems |
31 |
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3 Three-Membered Heterocycles |
33 |
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3.1 Oxirane |
33 |
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3.2 Thiirane |
42 |
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3.3 2H-Azirine |
45 |
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3.4 Aziridine |
48 |
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3.5 Dioxirane |
53 |
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3.6 Oxaziridine |
53 |
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3.7 3H-Diazirine |
56 |
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3.8 Diaziridine |
56 |
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References |
57 |
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4 Four-Membered Heterocyles |
61 |
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4.1 Oxetane |
61 |
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4.2 Thietane |
65 |
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4.3 Azete |
66 |
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4.4 Azetidine |
67 |
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4.5 1,2-Dioxetane |
70 |
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4.6 1,2-Dithiete |
73 |
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4.7 1,2-Dihydro-1,2-diazete |
74 |
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4.8 1,2-Diazetidine |
74 |
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References |
75 |
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5 Five-Membered Heterocycles |
77 |
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5.1 Furan |
77 |
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5.2 Benzo[b]furan |
96 |
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5.3 Isobenzofuran |
100 |
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5.4 Dibenzofuran |
102 |
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5.5 Tetrahydrofuran |
103 |
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5.6 Thiophene |
106 |
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5.7 Benzo[b]thiophene |
117 |
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5.8 Benzo[c]thiophene |
120 |
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5.9 2,5-Dihydrothiophene |
121 |
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5.10 Thiolane |
122 |
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5.11 Selenophene |
123 |
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5.12 Pyrrole |
124 |
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5.13 Indole |
141 |
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5.14 Carbazole |
164 |
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5.15 Isoindole |
166 |
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5.16 Indolizine |
168 |
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5.17 Pyrrolidine |
173 |
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5.18 Phosphole |
177 |
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5.19 1,3-Dioxolane |
178 |
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5.20 1,2-Dithiole |
179 |
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5.21 1,2-Dithiolane |
180 |
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5.22 1,3-Dithiole |
181 |
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5.23 1,3-Dithiolane |
181 |
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5.24 Oxazole |
182 |
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5.25 Benzoxazole |
193 |
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5.26 4,5-Dihydrooxazole |
197 |
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5.27 Isoxazole |
201 |
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5.28 4,5-Dihydroisoxazole |
209 |
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5.29 2,3-Dihydroisoxazole |
214 |
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5.30 Thiazole |
215 |
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5.31 Benzothiazole |
224 |
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5.32 Penam |
228 |
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5.33 Isothiazole |
230 |
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5.34 Imidazole |
233 |
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5.35 Benzimidazole |
245 |
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5.36 Imidazolidine |
250 |
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5.37 Pyrazole |
252 |
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5.38 Indazole |
259 |
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5.39 4,5-Dihydropyrazole |
262 |
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5.40 Pyrazolidine |
265 |
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5.41 1,2,3-, 1,2,4-, 1,3,4-Oxadiazole |
265 |
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5.42 1,2,5-Oxadiazole |
267 |
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5.43 1,2,3-Thiadiazole |
270 |
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5.44 1,2,4-Thiadiazole |
272 |
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5.45 1,2,3-Triazole |
274 |
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5.46 Benzotriazole |
281 |
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5.47 1,2,4-Triazole |
284 |
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5.48 Tetrazole |
289 |
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References |
296 |
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6 Six-Membered Heterocycles |
313 |
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6.1 Pyrylium Ion |
313 |
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6.2 2H-Pyran |
321 |
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6.3 2H-Pyran-2-one |
322 |
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6.4 3,4-Dihydro-2H-pyran |
329 |
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6.5 Tetrahydropyran |
333 |
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6.6 2H-Chromene |
335 |
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6.7 2H-Chromen-2-one |
337 |
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6.8 1-Benzopyrylium Ion |
343 |
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6.9 4H-Pyran |
345 |
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6.10 4H-Pyran-4-one |
347 |
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6.11 4H-Chromene |
351 |
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6.12 4H-Chromen-4-one |
352 |
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6.13 Chroman |
357 |
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6.14 Pyridine |
361 |
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6.15 Pyridones |
397 |
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6.16 Quinoline |
402 |
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6.17 Isoquinoline |
422 |
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6.18 Quinolizinium Ion |
436 |
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6.19 Dibenzopyridines |
439 |
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6.20 Piperidine |
445 |
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6.21 Phosphabenzene |
450 |
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6.22 1,4-Dioxin, 1,4-Dithiin, 1,4-Oxathiin |
454 |
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6.23 1,4-Dioxane |
456 |
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6.24 Oxazines |
458 |
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6.25 Morpholine |
463 |
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6.26 1,3-Dioxane |
465 |
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6.27 1,3-Dithiane |
469 |
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6.28 Cepham |
471 |
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6.29 Pyridazine |
474 |
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6.30 Pyrimidine |
479 |
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6.31 Purine |
490 |
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6.32 Pyrazine |
497 |
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6.33 Piperazine |
502 |
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6.34 Pteridine |
503 |
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6.35 Benzodiazines |
507 |
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6.36 1,2,3-Triazine |
517 |
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6.37 1,2,4-Triazine |
520 |
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6.38 1,3,5-Triazine |
524 |
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6.39 1,2,4,5-Tetrazine |
528 |
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References |
533 |
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7 Seven-Membered Heterocycles |
545 |
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7.1 Oxepin |
545 |
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7.2 Thiepin |
548 |
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7.3 Azepine |
549 |
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7.4 Diazepines |
556 |
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References |
561 |
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8 Larger Ring Heterocycles |
563 |
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8.1 Azocine |
563 |
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8.2 Heteronines and Larger-Membered Heterocycles |
565 |
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8.3 Tetrapyrroles |
567 |
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References |
574 |
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9 Problems and Their Solutions |
577 |
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References |
630 |
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Indices |
637 |
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