|
Preface |
6 |
|
|
Contents |
8 |
|
|
About the Editors |
12 |
|
|
Part IProperties and Functionalities of NaturalFibres and Structures |
13 |
|
|
1 Fibre Science: Understanding How It Works and Speculating on Its Future |
14 |
|
|
Abstract |
14 |
|
|
Introduction |
14 |
|
|
The Way Fibres and Fibrous Structures Work |
15 |
|
|
Impact of Emerging Sciences and Technologies in Fibre Science |
21 |
|
|
Speculating on Future Product Development |
23 |
|
|
Conclusions |
27 |
|
|
References |
27 |
|
|
2 Wool in Human Health and Well-Being |
29 |
|
|
Abstract |
29 |
|
|
Introduction |
29 |
|
|
Skin Health |
30 |
|
|
Physical Contact Between Textiles/Garments and Human Skin |
31 |
|
|
Thermal and Moisture Properties |
34 |
|
|
Human Body Odour---Textiles, Clothing, Footwear |
35 |
|
|
Sleep---Bed Clothes, Sleepwear, Bedding |
37 |
|
|
Conclusions |
39 |
|
|
Acknowledgments |
40 |
|
|
References |
40 |
|
|
3 Correlations Between the Physiochemical Characteristics of Plant Fibres and Their Mechanical Properties |
45 |
|
|
Abstract |
45 |
|
|
Introduction |
46 |
|
|
Experimental Procedures |
47 |
|
|
Materials |
47 |
|
|
Chemical Composition of Fibres |
47 |
|
|
Measurement of the Microfibril Angle |
48 |
|
|
Tensile Properties of Fibres |
48 |
|
|
Principal Component Analysis |
48 |
|
|
Results and Discussion |
49 |
|
|
Carbohydrate and Lignin Content of the Plant Fibres |
49 |
|
|
Measurement of the Plant Fibres Microfibril Angle |
50 |
|
|
Tensile Properties of Plant Fibres |
50 |
|
|
Damping Coefficient of Plant Fibres |
52 |
|
|
Determination of the Correlation Between Variables Using Principal Component Analysis |
53 |
|
|
Conclusions |
55 |
|
|
Acknowledgements |
55 |
|
|
References |
55 |
|
|
4 Influence of Stem Morphology and Fibres Stiffness on the Loading Stability of Flax |
58 |
|
|
Abstract |
58 |
|
|
Introduction |
58 |
|
|
Materials and Methods |
59 |
|
|
Results |
61 |
|
|
Stem Height and Fibre Yield |
61 |
|
|
Elementary Fibres Mechanical Properties |
62 |
|
|
Organization and Morphology of the Stems |
63 |
|
|
Correlation Between the Stem Stiffness or Morphology and the Fibre Mechanical Properties |
65 |
|
|
Conclusions |
67 |
|
|
Acknowledgments |
67 |
|
|
References |
67 |
|
|
5 Young's Modulus of Plant Fibers |
69 |
|
|
Abstract |
69 |
|
|
Introduction |
69 |
|
|
Decrease of the Young's Modulus as a Function of the Apparent Diameter of the Fiber |
70 |
|
|
Taking into Account the Presence of the Lumen |
72 |
|
|
Assuming the Presence of Another Structural Heterogeneity |
73 |
|
|
Conclusion |
76 |
|
|
References |
76 |
|
|
6 Characterization of Brazil Nut Fibers |
78 |
|
|
Abstract |
78 |
|
|
Introduction |
78 |
|
|
Materials and Methods |
80 |
|
|
Material |
80 |
|
|
Fiber Characterization |
80 |
|
|
Thermogravimetric Analysis (TG) |
81 |
|
|
Scanning Electron Microscopy (SEM) |
82 |
|
|
Wavelength Dispersive X-ray Fluorescence (WDXRF) Analysis |
82 |
|
|
Instrumental Neutron Activation Analysis (INAA) |
82 |
|
|
Results and Discussion |
83 |
|
|
Conclusion |
90 |
|
|
Acknowledgements |
91 |
|
|
References |
91 |
|
|
Part IINew, Functional and NanodimensionalNatural Fibres |
93 |
|
|
7 Brazilian Buriti Palm Fiber (Mauritia flexuosa Mart.) |
94 |
|
|
Abstract |
94 |
|
|
Introduction |
94 |
|
|
Buriti Palm Tree |
95 |
|
|
Collection, Processing and Traditional Employment |
96 |
|
|
Physicochemical Properties and New Employments |
100 |
|
|
Conclusion |
102 |
|
|
Acknowledgments |
102 |
|
|
References |
102 |
|
|
8 Degradation of Dyes Using Plantain Fibers Modified with Nanoparticles |
104 |
|
|
Abstract |
104 |
|
|
Introduction |
105 |
|
|
Plantain Crops in Colombia |
105 |
|
|
Current Applications of Plantain Fibers |
105 |
|
|
Contamination by Chemical Dyes |
107 |
|
|
Methodology |
107 |
|
|
Extraction of Fibers from Plantain Pseudostem |
107 |
|
|
Cationization Process |
108 |
|
|
Functionalization of Fibers |
110 |
|
|
Dye Degradation |
111 |
|
|
Results and Discussion |
111 |
|
|
Fibers Characterization |
111 |
|
|
Dye Degradation |
113 |
|
|
Discussion |
114 |
|
|
Conclusions |
115 |
|
|
References |
115 |
|
|
9 Removal of Crude Oil Using a New Natural Fibre---Calotropis procera |
117 |
|
|
Abstract |
117 |
|
|
Introduction |
118 |
|
|
Experimental Part |
120 |
|
|
Materials |
120 |
|
|
Calotropis procera Fibres |
120 |
|
|
Water Drop Absorption Test |
120 |
|
|
Petroleum |
121 |
|
|
Experimental Planning by Statistical Analysis |
121 |
|
|
Kinetic Study |
121 |
|
|
Results and Discussion |
122 |
|
|
Microstructural Characterization of Calotropis procera Fibre |
122 |
|
|
Characterization of Petroleum |
124 |
|
|
Statistical Analysis by RSM (Response Surface Methodology) |
125 |
|
|
Conclusion |
127 |
|
|
References |
128 |
|
|
10 Amazonian Tururi Palm Fiber Material (Manicaria saccifera Gaertn.) |
130 |
|
|
Abstract |
130 |
|
|
Introduction |
130 |
|
|
The Ubuçu Palm Tree |
131 |
|
|
Collection, Processing and Traditional Employment |
132 |
|
|
Physicochemical Properties and New Employments |
135 |
|
|
Conclusion |
138 |
|
|
Acknowledgments |
138 |
|
|
References |
139 |
|
|
11 Nanoindentation Measurements of Jute/Poly Lactic Acid Composites |
141 |
|
|
Abstract |
141 |
|
|
Overview of Present Situation |
141 |
|
|
Present State of Problems |
143 |
|
|
Experimental Methods |
144 |
|
|
Materials |
144 |
|
|
Pulverization of Jute Fibers to Nanofibers |
144 |
|
|
Preparation of Nanocomposite Films |
145 |
|
|
Testing of Nanocomposite Films |
145 |
|
|
Results and Conclusions |
146 |
|
|
Effect of Milling Condition on Particle Size Reduction of Jute Fibers |
146 |
|
|
Effect of Wet Milling Time on Particle Size Reduction of Jute Fibers |
148 |
|
|
Comparison of Size Measured on Different Techniques |
149 |
|
|
Nanoindentation Measurements |
150 |
|
|
Dynamic Mechanical Analysis |
153 |
|
|
Tensile Testing |
153 |
|
|
Conclusions |
155 |
|
|
References |
156 |
|
|
12 Biomedical Applications of Nanocellulose |
157 |
|
|
Abstract |
157 |
|
|
Introduction |
157 |
|
|
From Cellulose to Nanocellulose: Types of Nanocellulose |
158 |
|
|
Applications in Biomedical Field |
162 |
|
|
Conclusions and Remarks |
169 |
|
|
Acknowledgments |
169 |
|
|
References |
169 |
|
|
Part IIINatural Fibre Reinforced PolymericComposites |
172 |
|
|
13 A Finite Element Analysis to Validate the Rule-of-Mixtures for the Prediction of the Young's Modulus of Composites with Non-circular Anisotropic Fibres |
173 |
|
|
Abstract |
173 |
|
|
Introduction |
173 |
|
|
Finite Element Analysis (FEA) |
174 |
|
|
Poisson's Ratio |
178 |
|
|
Conclusions |
181 |
|
|
Acknowledgements |
181 |
|
|
References |
182 |
|
|
14 Effects of Water Ageing on the Mechanical Properties of Flax and Glass Fibre Composites: Degradation and Reversibility |
183 |
|
|
Abstract |
183 |
|
|
Introduction |
184 |
|
|
Materials and Methods |
185 |
|
|
Materials |
185 |
|
|
Resin and Fibres |
185 |
|
|
Chemical Treatment |
185 |
|
|
Vacuum Infusion Processing of Composite Sheets |
185 |
|
|
Methods |
186 |
|
|
Water Ageing Conditions |
186 |
|
|
Water Uptake, Volume and Density Variations |
186 |
|
|
Composites Drying |
187 |
|
|
Viscoelastic Properties Measured by Vibration Analysis |
187 |
|
|
Uniaxial Tensile Tests |
188 |
|
|
Scanning Electron Microscopy |
188 |
|
|
Differential Scanning Calorimetry |
188 |
|
|
Results and Discussion |
188 |
|
|
Conclusions |
194 |
|
|
References |
195 |
|
|
15 Processing of Wet Preserved Natural Fibers with Injection Molding Compounding (IMC) |
197 |
|
|
Abstract |
197 |
|
|
Introduction |
198 |
|
|
Novel Supply Chain for Fibrous Raw Materials |
199 |
|
|
Processing with IMC |
203 |
|
|
Processing, Sampling and Characterization of Products |
205 |
|
|
Summary |
208 |
|
|
Acknowledgments |
209 |
|
|
References |
209 |
|
|
16 Fluorination as an Effective Way to Reduce Natural Fibers Hydrophilicity |
211 |
|
|
Abstract |
211 |
|
|
Introduction |
212 |
|
|
Materials and Methods |
213 |
|
|
Materials |
213 |
|
|
Direct Fluorination of the Wood Flour |
213 |
|
|
FT-IR and NMR Spectroscopy |
214 |
|
|
TGA |
214 |
|
|
SEM Analysis |
214 |
|
|
X-ray Tomography |
215 |
|
|
Hygroscopic Testing of the Wood Flour |
215 |
|
|
Wood-Polyester Composite Processing |
216 |
|
|
Composite Mechanical Characterization |
216 |
|
|
Hygroscopic Behavior of the Composites |
217 |
|
|
Results and Discussion |
217 |
|
|
Covalent Grafting of Fluorine on Wood |
217 |
|
|
Decrease of Wood Hydrophilicity |
219 |
|
|
Preservation of the Structure of Wood |
221 |
|
|
Analysis of the Thermal Behavior of Wood |
221 |
|
|
Improvement of the Composite Health |
222 |
|
|
Improvement of the Composite Mechanical Properties |
222 |
|
|
Improvement of the Composite Hygroscopic Behavior |
224 |
|
|
Conclusions |
226 |
|
|
References |
227 |
|
|
17 DSC Analysis of In Situ Polymerized Poly(Butylene Terephthalate) Flax Fiber Reinforced Composites Produced by RTM |
230 |
|
|
Abstract |
230 |
|
|
Introduction |
230 |
|
|
Materials and Methods |
231 |
|
|
Materials |
231 |
|
|
RTM Set-up and Composite Manufacturing Details |
232 |
|
|
DSC Analysis |
233 |
|
|
Results and Discussion |
234 |
|
|
Production |
234 |
|
|
DSD Analysis |
235 |
|
|
Flax Fibers |
235 |
|
|
CBT 160 Resin |
236 |
|
|
pCBT Polymer |
237 |
|
|
Conclusions |
239 |
|
|
Acknowledgments |
239 |
|
|
References |
240 |
|
|
18 Parametric Study on the Manufacturing of Biocomposite Materials |
242 |
|
|
Abstract |
242 |
|
|
Introduction |
242 |
|
|
Materials |
245 |
|
|
Manufacturing |
246 |
|
|
Experimental Tests |
246 |
|
|
Results and Discussion |
246 |
|
|
Conclusions |
251 |
|
|
Acknowledgements |
252 |
|
|
References |
252 |
|
|
19 The Mechanical Properties of Flax Fibre Reinforced Composites |
254 |
|
|
Abstract |
254 |
|
|
Introduction |
254 |
|
|
Materials and Method |
257 |
|
|
Results |
258 |
|
|
Izod Impact |
258 |
|
|
Three Point Bending |
259 |
|
|
Electron Microscopy Studies |
261 |
|
|
Conclusions |
263 |
|
|
Acknowledgments |
264 |
|
|
References |
264 |
|
|
20 Eco-friendly Flax Fibre/Epoxy Resin/Composite System for Surfboard Production |
266 |
|
|
Abstract |
266 |
|
|
Introduction |
266 |
|
|
Experimental |
267 |
|
|
Materials Selection |
267 |
|
|
Laboratory Process |
268 |
|
|
Results |
270 |
|
|
Eco-surfboard Production |
270 |
|
|
Conclusion |
273 |
|
|
Future Work |
274 |
|
|
Acknowledgments |
274 |
|
|
References |
275 |
|
|
21 The Use of Cellulosic Fibers Wastes to Increase the Mechanical Behaviour of Biodegradable Composites for Automotive Interior Parts |
277 |
|
|
Abstract |
277 |
|
|
Introduction |
278 |
|
|
Materials and Methods |
279 |
|
|
Materials |
279 |
|
|
Preparation of the Composites |
280 |
|
|
Mechanical Characterization |
281 |
|
|
Tensile Properties Measurements |
281 |
|
|
Flexural Properties Measurements |
282 |
|
|
Instrumented Impact Properties Measurements |
282 |
|
|
Heat Deflection Temperature (HDT) Measurements |
282 |
|
|
Experimental Results and Remarks |
282 |
|
|
Conclusion and Final Remarks |
284 |
|
|
Acknowledgments |
285 |
|
|
References |
285 |
|
|
Part IVNatural Fibre Reinforced CementitiousComposites |
286 |
|
|
22 Hemp Fibres---A Promising Reinforcement for Cementitious Materials |
287 |
|
|
Abstract |
287 |
|
|
Introduction |
287 |
|
|
Materials and Methods |
289 |
|
|
Concrete and Hemp Fibres |
289 |
|
|
Experimental Program |
291 |
|
|
Results and Discussion |
292 |
|
|
Compression Strength |
292 |
|
|
Load---Crack Mouth Opening Displacement Curve |
293 |
|
|
Splitting Tensile Strength |
294 |
|
|
Energy Dissipation Capacity |
295 |
|
|
Conclusions |
296 |
|
|
Acknowledgments |
297 |
|
|
References |
297 |
|
|
23 Tensile and Bond Characterization of Natural Fibers Embeeded in Inorganic Matrices |
300 |
|
|
Abstract |
300 |
|
|
Introduction |
300 |
|
|
Materials and Specimens |
301 |
|
|
Test Methods |
304 |
|
|
Results and Discussion |
305 |
|
|
Mortar Properties |
305 |
|
|
Tensile Tests Results |
306 |
|
|
Pull-Out Tests Results |
307 |
|
|
Conclusions |
308 |
|
|
Acknowledgments |
309 |
|
|
References |
309 |
|
|
24 Eco-Efficient Earthen Plasters: The Influence of the Addition of Natural Fibers |
310 |
|
|
Abstract |
310 |
|
|
Introduction |
310 |
|
|
Materials |
312 |
|
|
Mortar's Formulations and Fresh State Characterization |
314 |
|
|
Hardened State Characterization |
314 |
|
|
Results and Discussion |
316 |
|
|
Conclusions |
320 |
|
|
Acknowledgments |
321 |
|
|
References |
321 |
|
|
Part VInnovative Applicationsof Natural Fibres |
323 |
|
|
25 Poly Lactic Acid Fibre Based Biodegradable Stents and Their Functionalization Techniques |
324 |
|
|
Abstract |
324 |
|
|
Introduction |
324 |
|
|
Natural-Based Stents |
326 |
|
|
PLLA Stents |
326 |
|
|
Chitosan Stents |
329 |
|
|
Stents Functionalization |
330 |
|
|
Layer by Layer |
331 |
|
|
Chitosan Coatings |
332 |
|
|
Conclusions |
334 |
|
|
Acknowledgments |
334 |
|
|
References |
334 |
|
|
26 Optimization of a Wood Plastic Composite to Produce a New Dynamic Shading System |
336 |
|
|
Abstract |
336 |
|
|
Introduction |
337 |
|
|
Dynamic Shading System Modeling |
338 |
|
|
Materials and Methods |
340 |
|
|
Materials |
341 |
|
|
Methods |
341 |
|
|
Results |
341 |
|
|
Conclusions |
343 |
|
|
References |
343 |
|
|
27 Biodegradation of Wool Used for the Production of Innovative Geotextiles Designed to Erosion Control |
344 |
|
|
Abstract |
344 |
|
|
Introduction |
344 |
|
|
Experimental |
346 |
|
|
Results and Conclusions |
348 |
|
|
Mechanical Parameters |
348 |
|
|
Fibres Morphology |
348 |
|
|
Fibres Composition |
351 |
|
|
Conslusions |
353 |
|
|
Acknowledgments |
353 |
|
|
References |
353 |
|
|
28 Renewable Materials for Stab Resistance |
355 |
|
|
Abstract |
355 |
|
|
Introduction |
355 |
|
|
Experimental |
356 |
|
|
Results |
358 |
|
|
Conclusion |
361 |
|
|
Acknowledgements |
361 |
|
|
References |
361 |
|
|
29 Hemp Fibre from Crops Grown on Reclaimed Land for the Production of Sanitary Mats |
363 |
|
|
Abstract |
363 |
|
|
Introduction |
363 |
|
|
Construction and the Properties of Sanitary Mats |
364 |
|
|
Materials and Methods |
365 |
|
|
Results and Discussion |
365 |
|
|
Conclusions |
368 |
|
|
References |
369 |
|
|
Part VIMarket, Opportunities, Recycling andSustainability Aspects of Natural Fibres |
370 |
|
|
30 Natural Fibres and the World Economy |
371 |
|
|
Abstract |
371 |
|
|
Introduction |
371 |
|
|
Wool |
373 |
|
|
Sisal |
374 |
|
|
Flax/Linen |
375 |
|
|
Hemp |
376 |
|
|
Cotton |
377 |
|
|
Jute and Kenaf |
378 |
|
|
Silk |
379 |
|
|
Other Natural Fibers |
380 |
|
|
Conclusions |
380 |
|
|
Acknowledgments |
380 |
|
|
References |
380 |
|
|
31 Wool as an Heirloom: How Natural Fibres Can Reinvent Value in Terms of Money, Life-Span and Love |
381 |
|
|
Abstract |
381 |
|
|
Imported Silk and Billowing Sails |
381 |
|
|
Growth Spiral and Circular Ideology |
382 |
|
|
Life Span and Love |
385 |
|
|
Monetary Value and Tradition---Elements of New BMs |
386 |
|
|
Norwegian Wool |
386 |
|
|
Scandinavian Business Seating---New Flexibility for Norwegian Wool and Local Production |
387 |
|
|
Sølv---New Twist on an Old Business Model |
389 |
|
|
Graveniid---New Use of Lapp Traditions, Northern Norway |
389 |
|
|
Maxhosa by Laduma---New Use of Xhosa Traditions, South Africa |
390 |
|
|
Selbu Mittens---New Thinking About Fair Price for Quality |
390 |
|
|
VikingGold---Reconquering the Vikings Textiles |
392 |
|
|
Conclusion: From Nature with Love |
393 |
|
|
Acknowledgements |
394 |
|
|
References |
394 |
|
|
32 Hemp Cultivation Opportunities and Perspectives in Lithuania |
396 |
|
|
Abstract |
396 |
|
|
Introduction |
397 |
|
|
Results and Discussion |
397 |
|
|
Hemp Cultivation Technology Opportunities |
397 |
|
|
Hemp Cultivation Perspectives in Lithuania |
399 |
|
|
Conclusions |
402 |
|
|
References |
403 |
|
|
33 Review of Wool Recycling and Reuse |
404 |
|
|
Abstract |
404 |
|
|
Introduction |
404 |
|
|
Collection and Sorting of Post-consumer Clothing |
404 |
|
|
Destinations of Post-consumer Clothing |
406 |
|
|
Heirloom Clothing Items |
407 |
|
|
Composition of Fibre Available for Recycling and Reuse |
407 |
|
|
Wool Fibre Recycling |
409 |
|
|
Open Loop Recycling of Wool Garments |
410 |
|
|
Closed Loop Recycling of Wool Garments |
412 |
|
|
Recycling of Corporate Clothing Containing Wool |
413 |
|
|
Case Studies |
414 |
|
|
References |
416 |
|
|
34 Brazilian Scope of Management and Recycling of Textile Wastes |
418 |
|
|
Abstract |
418 |
|
|
Introduction |
418 |
|
|
Mechanical Processes for Textile Recycling |
419 |
|
|
Recycled Cotton Yarn and Jeans |
420 |
|
|
The Generation of Textile Wastes in Brazil |
421 |
|
|
Incipient Brazilian Actions Toward the Sustainability |
424 |
|
|
Conclusion |
426 |
|
|
Acknowledgments |
426 |
|
|
References |
426 |
|
|
35 Cotton Dyeing with Extract from Renewable Agro Industrial Bio-resources: A Step Towards Sustainability |
429 |
|
|
Abstract |
429 |
|
|
Introduction |
429 |
|
|
General Approach |
429 |
|
|
Synthetic Dyes |
430 |
|
|
Natural Dyes |
430 |
|
|
Natural Dyes Chemistry |
430 |
|
|
Mordants |
431 |
|
|
Natural Mordants |
431 |
|
|
Acacia Dealbata |
432 |
|
|
Natural Dyes Benefits |
432 |
|
|
Environmental Sustainability |
432 |
|
|
Wastes: Source of Natural Dyes |
432 |
|
|
Olive Tree Culture |
433 |
|
|
Olive Tree Pruning Wastes |
433 |
|
|
Materials and Methods |
434 |
|
|
Cotton Pre-treatment |
434 |
|
|
Dyeing Bath Obtainment |
434 |
|
|
Dyeing Procedure |
434 |
|
|
Colour Assessment |
435 |
|
|
Colour-Fastness Evaluation |
435 |
|
|
Results and Conclusions |
435 |
|
|
Extraction of Different Materials Studied |
435 |
|
|
Dyeing Results |
436 |
|
|
Extracted Temperature Solution and Material Conditions |
436 |
|
|
pH Effect of Dyeing Solutions in Colour Strength |
436 |
|
|
Effect of Electrolyte and Mordant (Inorganic and Organic) on K/S |
436 |
|
|
Colour Coordinates and Colour-Fastness Results |
438 |
|
|
Conclusions |
438 |
|
|
References |
440 |
|
|
36 Erratum to: Review of Wool Recycling and Reuse |
442 |
|
|
Erratum to: ‘Review of Wool Recycling and Reuse’ R. Fangueiro and S. Rana (eds.), Natural Fibres: Advances in Science and Technology Towards Industrial Applications, RILEM Bookseries 12, DOI 10.1007/978-94-017-7515-1_33 |
442 |
|
|
Index |
443 |
|