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Chemical Process Design and Integration
  Großes Bild
 
Chemical Process Design and Integration
von: Robin Smith
Wiley, 2016
ISBN: 9781118699096
928 Seiten, Download: 170725 KB
 
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Inhaltsverzeichnis

  Title Page 5  
  Copyright Page 6  
  Contents 9  
  Preface to the Second Edition 211  
  Acknowledgements 887  
  Nomenclature 837  
  Chapter 1: The Nature of Chemical Process Design and Integration 27  
     1.1 Chemical Products 27  
     1.2 Formulation of Design Problems 29  
     1.3 Synthesis and Simulation 30  
     1.4 The Hierarchy of Chemical Process Design and Integration 32  
     1.5 Continuous and Batch Processes 34  
     1.6 New Design and Retrofit 37  
     1.7 Reliability, Availability and Maintainability 37  
     1.8 Process Control 38  
     1.9 Approaches to Chemical Process Design and Integration 39  
     1.10 The Nature of Chemical Process Design and Integration – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 42  
     References 43  
  Chapter 2: Process Economics 603  
     2.1 The Role of Process Economics 45  
     2.2 Capital Cost for New Design 45  
     2.3 Capital Cost for Retrofit 51  
     2.4 Annualized Capital Cost 52  
     2.5 Operating Cost 53  
     2.6 Simple Economic Criteria 56  
     2.7 Project Cash Flow and Economic Evaluation 57  
     2.8 Investment Criteria 59  
     2.9 Process Economics – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 60  
     2.10 Exercises 60  
     References 62  
  Chapter 3: Optimization 603  
     3.1 Objective Functions 63  
     3.2 Single–Variable Optimization???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 66  
     3.3 Multivariable Optimization 68  
     3.4 Constrained Optimization 71  
     3.5 Linear Programming 73  
     3.6 Nonlinear Programming 75  
     3.7 Structural Optimization 76  
     3.8 Solution of Equations Using Optimization 80  
     3.9 The Search for Global Optimality 81  
     3.10 Optimization – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 82  
     3.11 Exercises 82  
     References 84  
  Chapter 4: Chemical Reactors I – Reactor Performance???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 589  
     4.1 Reaction Path 85  
     4.2 Types of Reaction Systems 87  
     4.3 Measures of Reactor Performance 89  
     4.4 Rate of Reaction 90  
     4.5 Idealized Reactor Models 91  
     4.6 Choice of Idealized Reactor Model 99  
     4.7 Choice of Reactor Performance 102  
     4.8 Reactor Performance – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 103  
     4.9 Exercises 104  
     References 105  
  Chapter 5: Chemical Reactors II – Reactor Conditions???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 107  
     5.1 Reaction Equilibrium 107  
     5.2 Reactor Temperature 111  
     5.3 Reactor Pressure 118  
     5.4 Reactor Phase 119  
     5.5 Reactor Concentration 120  
     5.6 Biochemical Reactions 125  
     5.7 Catalysts 125  
     5.8 Reactor Conditions – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 128  
     5.9 Exercises 129  
     References 131  
  Chapter 6: Chemical Reactors III – Reactor Configuration???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 133  
     6.1 Temperature Control 133  
     6.2 Catalyst Degradation 137  
     6.3 Gas–Liquid and Liquid–Liquid Reactors?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 138  
     6.4 Reactor Configuration 142  
     6.5 Reactor Configuration For Heterogeneous Solid-Catalyzed Reactions 147  
     6.6 Reactor Configuration Summary 148  
     6.7 Exercises 148  
     References 149  
  Chapter 7: Separation of Heterogeneous Mixtures 151  
     7.1 Homogeneous and Heterogeneous Separation 151  
     7.2 Settling and Sedimentation 152  
     7.3 Inertial and Centrifugal Separation 156  
     7.4 Electrostatic Precipitation 157  
     7.5 Filtration 159  
     7.6 Scrubbing 160  
     7.7 Flotation 161  
     7.8 Drying 162  
     7.9 Separation of Heterogeneous Mixtures – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 163  
     7.10 Exercises 163  
     References 164  
  Chapter 8: Separation of Homogeneous Fluid Mixtures I – Distillation???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 713  
     8.1 Vapor–Liquid Equilibrium???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 165  
     8.2 Calculation of Vapor-Liquid Equilibrium 167  
     8.3 Single-Stage Separation 172  
     8.4 Distillation 172  
     8.5 Binary Distillation 176  
     8.6 Total and Minimum Reflux Conditions for Multicomponent Mixtures 181  
     8.7 Finite Reflux Conditions for Multicomponent Mixtures 188  
     8.8 Column Dimensions 190  
     8.9 Conceptual Design of Distillation 200  
     8.10 Detailed Design of Distillation 202  
     8.11 Limitations of Distillation 205  
     8.12 Separation of Homogeneous Fluid Mixtures by Distillation – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 206  
     8.13 Exercises 206  
     References 209  
  Chapter 9: Separation of Homogeneous Fluid Mixtures II – Other Methods???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 211  
     9.1 Absorption and Stripping 211  
     9.2 Liquid–Liquid Extraction???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 215  
     9.3 Adsorption 222  
     9.4 Membranes 225  
     9.5 Crystallization 237  
     9.6 Evaporation 241  
     9.7 Separation of Homogeneous Fluid Mixtures by Other Methods – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 243  
     9.8 Exercises 243  
     References 245  
  Chapter 10: Distillation Sequencing 247  
     10.1 Distillation Sequencing using Simple Columns 247  
     10.2 Practical Constraints Restricting Options 247  
     10.3 Choice of Sequence for Simple Nonintegrated Distillation Columns 248  
     10.4 Distillation Sequencing using Columns With More Than Two Products 255  
     10.5 Distillation Sequencing using Thermal Coupling 257  
     10.6 Retrofit of Distillation Sequences 262  
     10.7 Crude Oil Distillation 263  
     10.8 Structural Optimization of Distillation Sequences 265  
     10.9 Distillation Sequencing – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 268  
     10.10 Exercises 268  
     References 271  
  Chapter 11: Distillation Sequencing for Azeotropic Distillation 891  
     11.1 Azeotropic Systems 273  
     11.2 Change in Pressure 273  
     11.3 Representation of Azeotropic Distillation 274  
     11.4 Distillation at Total Reflux Conditions 276  
     11.5 Distillation at Minimum Reflux Conditions 281  
     11.6 Distillation at Finite Reflux Conditions 282  
     11.7 Distillation Sequencing Using an Entrainer 285  
     11.8 Heterogeneous Azeotropic Distillation 290  
     11.9 Entrainer Selection 293  
     11.10 Multicomponent Systems 296  
     11.11 Trade-Offs in Azeotropic Distillation 296  
     11.12 Membrane Separation 296  
     11.13 Distillation Sequencing for Azeotropic Distillation – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 297  
     11.14 Exercises 298  
     References 299  
  Chapter 12: Heat Exchange 301  
     12.1 Overall Heat Transfer Coefficients 301  
     12.2 Heat Exchanger Fouling 305  
     12.3 Temperature Differences in Shell-and-Tube Heat Exchangers 307  
     12.4 Heat Exchanger Geometry 314  
     12.5 Allocation of Fluids in Shell-and-Tube Heat Exchangers 320  
     12.6 Heat Transfer Coefficients and Pressure Drops in Shell-and-Tube Heat Exchangers 320  
     12.7 Rating and Simulation of Heat Exchangers 327  
     12.8 Heat Transfer Enhancement 333  
     12.9 Retrofit of Heat Exchangers 339  
     12.10 Condensers 342  
     12.11 Reboilers and Vaporizers 347  
     12.12 Other Types of Heat Exchangers 352  
     12.13 Fired Heaters 354  
     12.14 Heat Exchange – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 371  
     12.15 Exercises 372  
     References 374  
  Chapter 13: Pumping and Compression 375  
     13.1 Pressure Drops in Process Operations 375  
     13.2 Pressure Drops in Piping Systems 375  
     13.3 Pump Types 381  
     13.4 Centrifugal Pump Performance 382  
     13.5 Compressor Types 389  
     13.6 Reciprocating Compressors 392  
     13.7 Dynamic Compressors 393  
     13.8 Staged Compression 395  
     13.9 Compressor Performance 396  
     13.10 Process Expanders 398  
     13.11 Pumping and Compression – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 400  
     13.12 Exercises 400  
     References 401  
  Chapter 14: Continuous Process Recycle Structure 887  
     14.1 The Function of Process Recycles 403  
     14.2 Recycles with Purges 408  
     14.3 Hybrid Reaction and Separation 411  
     14.4 The Process Yield 412  
     14.5 Feed, Product and Intermediate Storage 414  
     14.6 Continuous Process Recycle Structure – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 415  
     14.7 Exercises 415  
     References 417  
  Chapter 15: Continuous Process Simulation and Optimization 419  
     15.1 Physical Property Models for Process Simulation 419  
     15.2 Unit Models for Process Simulation 420  
     15.3 Flowsheet Models 426  
     15.4 Simulation of Recycles 426  
     15.5 Convergence of Recycles 428  
     15.6 Design Specifications 434  
     15.7 Flowsheet Sequencing 434  
     15.8 Model Validation 434  
     15.9 Process Optimization 434  
     15.10 Continuous Process Simulation and Optimization – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 439  
     15.11 Exercises 439  
     References 442  
  Chapter 16: Batch Processes 887  
     16.1 Characteristics of Batch Processes 443  
     16.2 Batch Reactors 443  
     16.3 Batch Distillation 446  
     16.4 Batch Crystallization 457  
     16.5 Batch Filtration 458  
     16.6 Batch Heating and Cooling 459  
     16.7 Optimization of Batch Operations 462  
     16.8 Gantt Charts 468  
     16.9 Production Schedules for Single Products 468  
     16.10 Production Schedules for Multiple Products 470  
     16.11 Equipment Cleaning and Material Transfer 471  
     16.12 Synthesis of Reaction and Separation Systems for Batch Processes 472  
     16.13 Storage in Batch Processes 478  
     16.14 Batch Processes – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 478  
     16.15 Exercises 478  
     References 481  
  Chapter 17: Heat Exchanger Networks I – Network Targets?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 907  
     17.1 Composite Curves 483  
     17.2 The Heat Recovery Pinch 487  
     17.3 Threshold Problems 490  
     17.4 The Problem Table Algorithm 492  
     17.5 Non–global Minimum Temperature Differences?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 498  
     17.6 Process Constraints 499  
     17.7 Utility Selection 501  
     17.8 Furnaces 503  
     17.9 Cogeneration (Combined Heat and Power Generation) 506  
     17.10 Integration of Heat Pumps 511  
     17.11 Number of Heat Exchange Units 512  
     17.12 Heat Exchange Area Targets 515  
     17.13 Sensitivity of Targets 519  
     17.14 Capital and Total Cost Targets 519  
     17.15 Heat Exchanger Network Targets – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 522  
     17.16 Exercises 522  
     References 525  
  Chapter 18: Heat Exchanger Networks II – Network Design 133  
     18.1 The Pinch Design Method 527  
     18.2 Design for Threshold Problems 533  
     18.3 Stream Splitting 533  
     18.4 Design for Multiple Pinches 537  
     18.5 Remaining Problem Analysis 542  
     18.6 Simulation of Heat Exchanger Networks 544  
     18.7 Optimization of a Fixed Network Structure 546  
     18.8 Automated Methods of Heat Exchanger Network Design 549  
     18.9 Heat Exchanger Network Retrofit with a Fixed Network Structure 551  
     18.10 Heat Exchanger Network Retrofit through Structural Changes 556  
     18.11 Automated Methods of Heat Exchanger Network Retrofit 562  
     18.12 Heat Exchanger Network Design – Summary 564  
     18.13 Exercises 565  
     References 568  
  Chapter 19: Heat Exchanger Networks III – Stream Data 569  
     19.1 Process Changes for Heat Integration 569  
     19.2 The Trade–Offs Between Process Changes, Utility Selection, Energy Cost and Capital Cost???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 569  
     19.3 Data Extraction 570  
     19.4 Heat Exchanger Network Stream Data – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 577  
     19.5 Exercises 577  
     References 579  
  Chapter 20: Heat Integration of Reactors 581  
     20.1 The Heat Integration Characteristics of Reactors 581  
     20.2 Appropriate Placement of Reactors 583  
     20.3 Use of the Grand Composite Curve for Heat Integration of Reactors 584  
     20.4 Evolving Reactor Design to Improve Heat Integration 586  
     20.5 Heat Integration of Reactors – Summary 587  
     20.6 Exercises 587  
     Reference 587  
  Chapter 21: Heat Integration of Distillation 589  
     21.1 The Heat Integration Characteristics of Distillationƒ 589  
     21.2 The Appropriate Placement of Distillation 589  
     21.3 Use of the Grand Composite Curve for Heat Integration of Distillation 590  
     21.4 Evolving the Design of Simple Distillation Columns to Improve Heat Integration 590  
     21.5 Heat Pumping in Distillation 593  
     21.6 Capital Cost Considerations for the Integration of Distillation 593  
     21.7 Heat Integration Characteristics of Distillation Sequences 594  
     21.8 Design of Heat Integrated Distillation Sequences 597  
     21.9 Heat Integration of Distillation – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 598  
     21.10 Exercises 598  
     References 601  
  Chapter 22: Heat Integration of Evaporators and Dryers 603  
     22.1 The Heat Integration Characteristics of Evaporators 603  
     22.2 Appropriate Placement of Evaporators 603  
     22.3 Evolving Evaporator Design to Improve Heat Integration 603  
     22.4 The Heat Integration Characteristics of Dryers 605  
     22.5 Evolving Dryer Design to Improve Heat Integration 605  
     22.6 A Case Study 607  
     22.7 Heat Integration of Evaporators and Dryers – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 607  
     22.8 Exercises 608  
     References 608  
  Chapter 23: Steam Systems and Cogeneration 151  
     23.1 Boiler Feedwater Treatment 611  
     23.2 Steam Boilers 615  
     23.3 Gas Turbines 621  
     23.4 Steam Turbines 628  
     23.5 Steam Distribution 635  
     23.6 Site Composite Curves 638  
     23.7 Cogeneration Targets 649  
     23.8 Power Generation and Machine Drives 653  
     23.9 Utility Simulation 657  
     23.10 Optimizing Steam Systems 659  
     23.11 Steam Costs 664  
     23.12 Steam Systems and Cogeneration – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 667  
     23.13 Exercises 668  
     References 671  
  Chapter 24: Cooling and Refrigeration Systems 581  
     24.1 Cooling Systems 673  
     24.2 Once-Through Water Cooling 673  
     24.3 Recirculating Cooling Water Systems 673  
     24.4 Air Coolers 676  
     24.5 Refrigeration 682  
     24.6 Choice of a Single-Component Refrigerant for Compression Refrigeration 688  
     24.7 Targeting Refrigeration Power for Pure Component Compression Refrigeration 691  
     24.8 Heat Integration of Pure Component Compression Refrigeration Processes 695  
     24.9 Mixed Refrigerants for Compression Refrigeration 699  
     24.10 Expanders 703  
     24.11 Absorption Refrigeration 707  
     24.12 Indirect Refrigeration 708  
     24.13 Cooling Water and Refrigeration Systems – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 708  
     24.14 Exercises 709  
     References 711  
  Chapter 25: Environmental Design for Atmospheric Emissions 713  
     25.1 Atmospheric Pollution 713  
     25.2 Sources of Atmospheric Pollution 714  
     25.3 Control of Solid Particulate Emissions to Atmosphere 716  
     25.4 Control of VOC Emissions 716  
     25.5 Control of Sulfur Emissions 729  
     25.6 Control of Oxides of Nitrogen Emissions 734  
     25.7 Control of Combustion Emissions 737  
     25.8 Atmospheric Dispersion 740  
     25.9 Environmental Design for Atmospheric Emissions – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 742  
     25.10 Exercises 743  
     References 746  
  Chapter 26: Water System Design 747  
     26.1 Aqueous Contamination 750  
     26.2 Primary Treatment Processes 751  
     26.3 Biological Treatment Processes 755  
     26.4 Tertiary Treatment Processes 758  
     26.5 Water Use 759  
     26.6 Targeting for Maximum Water Reuse for Single Contaminants for Operations with Fixed Mass Loads 761  
     26.7 Design for Maximum Water Reuse for Single Contaminants for Operations with Fixed Mass Loads 763  
     26.8 Targeting for Maximum Water Reuse for Single Contaminants for Operations with Fixed Flowrates 773  
     26.9 Design for Maximum Water Reuse for Single Contaminants for Operations with Fixed Flowrates 777  
     26.10 Targeting and Design for Maximum Water Reuse Based on Optimization of a Superstructure 784  
     26.11 Process Changes for Reduced Water Consumption 786  
     26.12 Targeting for Minimum Wastewater Treatment Flowrate for Single Contaminants 787  
     26.13 Design for Minimum Wastewater Treatment Flowrate for Single Contaminants 791  
     26.14 Regeneration of Wastewater 793  
     26.15 Targeting and Design for Effluent Treatment and Regeneration Based on Optimization of a Superstructure 798  
     26.16 Data Extraction 799  
     26.17 Water System Design – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 801  
     26.18 Exercises 802  
     References 805  
  Chapter 27: Environmental Sustainability in Chemical Production 807  
     27.1 Life Cycle Assessment 807  
     27.2 Efficient Use of Raw Materials Within Processes 812  
     27.3 Efficient Use of Raw Materials Between Processes 818  
     27.4 Exploitation of Renewable Raw Materials 820  
     27.5 Efficient Use of Energy 821  
     27.6 Integration of Waste Treatment and Energy Sytems 831  
     27.7 Renewable Energy 832  
     27.8 Efficient Use of Water 833  
     27.9 Sustainability in Chemical Production – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 833  
     27.10 Exercises 834  
     References 835  
  Chapter 28: Process Safety 837  
     28.1 Fire 837  
     28.2 Explosion 838  
     28.3 Toxic Release 839  
     28.4 Hazard Identification 839  
     28.5 The Hierarchy of Safety Management 841  
     28.6 Inherently Safer Design 841  
     28.7 Layers of Protection 845  
     28.8 Hazard and Operability Studies 848  
     28.9 Layer of Protection Analysis 849  
     28.10 Process Safety – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? 849  
     28.11 Exercises 850  
     References 851  
  Appendix A: Physical Properties in Process Design 853  
     A.1 Equations of State 853  
     A.2 Phase Equilibrium for Single Components 857  
     A.3 Fugacity and Phase Equilibrium 857  
     A.4 Vapor–Liquid Equilibrium 857  
     A.5 Vapor–Liquid Equilibrium Based on Activity Coefficient Models 859  
     A.6 Group Contribution Methods for Vapor–Liquid Equilibrium 861  
     A.7 Vapor–Liquid Equilibrium Based on Equations of State 863  
     A.8 Calculation of Vapor–Liquid Equilibrium 864  
     A.9 Liquid–Liquid Equilibrium 867  
     A.10 Liquid–Liquid Equilibrium Activity Coefficient Models 868  
     A.11 Calculation of Liquid–Liquid Equilibrium 868  
     A.12 Choice of Method for Equilibrium Calculations 870  
     A.13 Calculation of Enthalpy 872  
     A.14 Calculation of Entropy 873  
     A.15 Other Physical Properties 874  
     A.16 Physical Properties in Process Design – Summary 876  
     A.17 Exercises 877  
     References 878  
  Appendix B: Materials of Construction 581  
     B.1 Mechanical Properties 879  
     B.2 Corrosion 880  
     B.3 Corrosion Allowance 881  
     B.4 Commonly used Materials of Construction 881  
     B.5 Criteria for Selection 885  
     B.6 Materials of Construction – Summary 886  
     References 886  
  Appendix C: Annualization of Capital Cost 887  
     Reference 887  
  Appendix D: The Maximum Thermal Effectiveness for 1–2 Shell-and-Tube Heat Exchangers 27  
     References 889  
  Appendix E: Expression for the Minimum Number of 1–2 Shell-and-Tube Heat Exchangers for a Given Unit 891  
     References 892  
  Appendix F: Heat Transfer Coefficient and Pressure Drop in Shell-and-Tube Heat Exchangers 893  
     F.1 Heat Transfer and Pressure Drop Correlations for the Tube Side 893  
     F.2 Heat Transfer and Pressure Drop Correlations for the Shell Side 895  
     References 899  
  Appendix G: Gas Compression Theory 837  
     G.1 Modeling Reciprocating Compressors 901  
     G.2 Modeling Dynamic Compressors 903  
     G.3 Staged Compression 903  
     References 905  
  Appendix H: Algorithm for the Heat Exchanger Network Area Target 907  
  Index 211  
  EULA 923  


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