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Title Page |
5 |
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Copyright Page |
6 |
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Contents |
9 |
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Preface to the Second Edition |
211 |
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Acknowledgements |
887 |
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Nomenclature |
837 |
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Chapter 1: The Nature of Chemical Process Design and Integration |
27 |
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1.1 Chemical Products |
27 |
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1.2 Formulation of Design Problems |
29 |
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1.3 Synthesis and Simulation |
30 |
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1.4 The Hierarchy of Chemical Process Design and Integration |
32 |
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1.5 Continuous and Batch Processes |
34 |
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1.6 New Design and Retrofit |
37 |
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1.7 Reliability, Availability and Maintainability |
37 |
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1.8 Process Control |
38 |
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1.9 Approaches to Chemical Process Design and Integration |
39 |
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1.10 The Nature of Chemical Process Design and Integration – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
42 |
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References |
43 |
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Chapter 2: Process Economics |
603 |
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2.1 The Role of Process Economics |
45 |
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2.2 Capital Cost for New Design |
45 |
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2.3 Capital Cost for Retrofit |
51 |
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2.4 Annualized Capital Cost |
52 |
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2.5 Operating Cost |
53 |
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2.6 Simple Economic Criteria |
56 |
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2.7 Project Cash Flow and Economic Evaluation |
57 |
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2.8 Investment Criteria |
59 |
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2.9 Process Economics – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
60 |
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2.10 Exercises |
60 |
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References |
62 |
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Chapter 3: Optimization |
603 |
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3.1 Objective Functions |
63 |
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3.2 Single–Variable Optimization???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
66 |
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3.3 Multivariable Optimization |
68 |
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3.4 Constrained Optimization |
71 |
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3.5 Linear Programming |
73 |
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3.6 Nonlinear Programming |
75 |
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3.7 Structural Optimization |
76 |
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3.8 Solution of Equations Using Optimization |
80 |
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3.9 The Search for Global Optimality |
81 |
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3.10 Optimization – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
82 |
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3.11 Exercises |
82 |
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References |
84 |
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Chapter 4: Chemical Reactors I – Reactor Performance???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
589 |
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4.1 Reaction Path |
85 |
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4.2 Types of Reaction Systems |
87 |
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4.3 Measures of Reactor Performance |
89 |
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4.4 Rate of Reaction |
90 |
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4.5 Idealized Reactor Models |
91 |
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4.6 Choice of Idealized Reactor Model |
99 |
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4.7 Choice of Reactor Performance |
102 |
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4.8 Reactor Performance – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
103 |
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4.9 Exercises |
104 |
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References |
105 |
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Chapter 5: Chemical Reactors II – Reactor Conditions???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
107 |
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5.1 Reaction Equilibrium |
107 |
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5.2 Reactor Temperature |
111 |
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5.3 Reactor Pressure |
118 |
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5.4 Reactor Phase |
119 |
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5.5 Reactor Concentration |
120 |
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5.6 Biochemical Reactions |
125 |
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5.7 Catalysts |
125 |
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5.8 Reactor Conditions – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
128 |
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5.9 Exercises |
129 |
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References |
131 |
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Chapter 6: Chemical Reactors III – Reactor Configuration???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
133 |
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6.1 Temperature Control |
133 |
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6.2 Catalyst Degradation |
137 |
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6.3 Gas–Liquid and Liquid–Liquid Reactors?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
138 |
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6.4 Reactor Configuration |
142 |
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6.5 Reactor Configuration For Heterogeneous Solid-Catalyzed Reactions |
147 |
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6.6 Reactor Configuration Summary |
148 |
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6.7 Exercises |
148 |
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References |
149 |
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Chapter 7: Separation of Heterogeneous Mixtures |
151 |
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7.1 Homogeneous and Heterogeneous Separation |
151 |
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7.2 Settling and Sedimentation |
152 |
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7.3 Inertial and Centrifugal Separation |
156 |
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7.4 Electrostatic Precipitation |
157 |
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7.5 Filtration |
159 |
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7.6 Scrubbing |
160 |
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7.7 Flotation |
161 |
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7.8 Drying |
162 |
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7.9 Separation of Heterogeneous Mixtures – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
163 |
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7.10 Exercises |
163 |
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References |
164 |
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Chapter 8: Separation of Homogeneous Fluid Mixtures I – Distillation???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
713 |
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8.1 Vapor–Liquid Equilibrium???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
165 |
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8.2 Calculation of Vapor-Liquid Equilibrium |
167 |
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8.3 Single-Stage Separation |
172 |
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8.4 Distillation |
172 |
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8.5 Binary Distillation |
176 |
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8.6 Total and Minimum Reflux Conditions for Multicomponent Mixtures |
181 |
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8.7 Finite Reflux Conditions for Multicomponent Mixtures |
188 |
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8.8 Column Dimensions |
190 |
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8.9 Conceptual Design of Distillation |
200 |
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8.10 Detailed Design of Distillation |
202 |
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8.11 Limitations of Distillation |
205 |
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8.12 Separation of Homogeneous Fluid Mixtures by Distillation – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
206 |
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8.13 Exercises |
206 |
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References |
209 |
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Chapter 9: Separation of Homogeneous Fluid Mixtures II – Other Methods???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
211 |
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9.1 Absorption and Stripping |
211 |
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9.2 Liquid–Liquid Extraction???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
215 |
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9.3 Adsorption |
222 |
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9.4 Membranes |
225 |
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9.5 Crystallization |
237 |
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9.6 Evaporation |
241 |
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9.7 Separation of Homogeneous Fluid Mixtures by Other Methods – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
243 |
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9.8 Exercises |
243 |
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References |
245 |
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Chapter 10: Distillation Sequencing |
247 |
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10.1 Distillation Sequencing using Simple Columns |
247 |
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10.2 Practical Constraints Restricting Options |
247 |
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10.3 Choice of Sequence for Simple Nonintegrated Distillation Columns |
248 |
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10.4 Distillation Sequencing using Columns With More Than Two Products |
255 |
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10.5 Distillation Sequencing using Thermal Coupling |
257 |
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10.6 Retrofit of Distillation Sequences |
262 |
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10.7 Crude Oil Distillation |
263 |
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10.8 Structural Optimization of Distillation Sequences |
265 |
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10.9 Distillation Sequencing – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
268 |
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10.10 Exercises |
268 |
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References |
271 |
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Chapter 11: Distillation Sequencing for Azeotropic Distillation |
891 |
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11.1 Azeotropic Systems |
273 |
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11.2 Change in Pressure |
273 |
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11.3 Representation of Azeotropic Distillation |
274 |
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11.4 Distillation at Total Reflux Conditions |
276 |
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11.5 Distillation at Minimum Reflux Conditions |
281 |
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11.6 Distillation at Finite Reflux Conditions |
282 |
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11.7 Distillation Sequencing Using an Entrainer |
285 |
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11.8 Heterogeneous Azeotropic Distillation |
290 |
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11.9 Entrainer Selection |
293 |
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11.10 Multicomponent Systems |
296 |
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11.11 Trade-Offs in Azeotropic Distillation |
296 |
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11.12 Membrane Separation |
296 |
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11.13 Distillation Sequencing for Azeotropic Distillation – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
297 |
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11.14 Exercises |
298 |
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References |
299 |
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|
Chapter 12: Heat Exchange |
301 |
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12.1 Overall Heat Transfer Coefficients |
301 |
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12.2 Heat Exchanger Fouling |
305 |
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12.3 Temperature Differences in Shell-and-Tube Heat Exchangers |
307 |
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12.4 Heat Exchanger Geometry |
314 |
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12.5 Allocation of Fluids in Shell-and-Tube Heat Exchangers |
320 |
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12.6 Heat Transfer Coefficients and Pressure Drops in Shell-and-Tube Heat Exchangers |
320 |
|
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12.7 Rating and Simulation of Heat Exchangers |
327 |
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12.8 Heat Transfer Enhancement |
333 |
|
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12.9 Retrofit of Heat Exchangers |
339 |
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12.10 Condensers |
342 |
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|
12.11 Reboilers and Vaporizers |
347 |
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12.12 Other Types of Heat Exchangers |
352 |
|
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12.13 Fired Heaters |
354 |
|
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12.14 Heat Exchange – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
371 |
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12.15 Exercises |
372 |
|
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References |
374 |
|
|
Chapter 13: Pumping and Compression |
375 |
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|
13.1 Pressure Drops in Process Operations |
375 |
|
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13.2 Pressure Drops in Piping Systems |
375 |
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13.3 Pump Types |
381 |
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13.4 Centrifugal Pump Performance |
382 |
|
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13.5 Compressor Types |
389 |
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13.6 Reciprocating Compressors |
392 |
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13.7 Dynamic Compressors |
393 |
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13.8 Staged Compression |
395 |
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13.9 Compressor Performance |
396 |
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13.10 Process Expanders |
398 |
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13.11 Pumping and Compression – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
400 |
|
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13.12 Exercises |
400 |
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References |
401 |
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Chapter 14: Continuous Process Recycle Structure |
887 |
|
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14.1 The Function of Process Recycles |
403 |
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14.2 Recycles with Purges |
408 |
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14.3 Hybrid Reaction and Separation |
411 |
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14.4 The Process Yield |
412 |
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14.5 Feed, Product and Intermediate Storage |
414 |
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14.6 Continuous Process Recycle Structure – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
415 |
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14.7 Exercises |
415 |
|
|
References |
417 |
|
|
Chapter 15: Continuous Process Simulation and Optimization |
419 |
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15.1 Physical Property Models for Process Simulation |
419 |
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15.2 Unit Models for Process Simulation |
420 |
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15.3 Flowsheet Models |
426 |
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15.4 Simulation of Recycles |
426 |
|
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15.5 Convergence of Recycles |
428 |
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15.6 Design Specifications |
434 |
|
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15.7 Flowsheet Sequencing |
434 |
|
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15.8 Model Validation |
434 |
|
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15.9 Process Optimization |
434 |
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15.10 Continuous Process Simulation and Optimization – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
439 |
|
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15.11 Exercises |
439 |
|
|
References |
442 |
|
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Chapter 16: Batch Processes |
887 |
|
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16.1 Characteristics of Batch Processes |
443 |
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16.2 Batch Reactors |
443 |
|
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16.3 Batch Distillation |
446 |
|
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16.4 Batch Crystallization |
457 |
|
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16.5 Batch Filtration |
458 |
|
|
16.6 Batch Heating and Cooling |
459 |
|
|
16.7 Optimization of Batch Operations |
462 |
|
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16.8 Gantt Charts |
468 |
|
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16.9 Production Schedules for Single Products |
468 |
|
|
16.10 Production Schedules for Multiple Products |
470 |
|
|
16.11 Equipment Cleaning and Material Transfer |
471 |
|
|
16.12 Synthesis of Reaction and Separation Systems for Batch Processes |
472 |
|
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16.13 Storage in Batch Processes |
478 |
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16.14 Batch Processes – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
478 |
|
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16.15 Exercises |
478 |
|
|
References |
481 |
|
|
Chapter 17: Heat Exchanger Networks I – Network Targets?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
907 |
|
|
17.1 Composite Curves |
483 |
|
|
17.2 The Heat Recovery Pinch |
487 |
|
|
17.3 Threshold Problems |
490 |
|
|
17.4 The Problem Table Algorithm |
492 |
|
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17.5 Non–global Minimum Temperature Differences?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
498 |
|
|
17.6 Process Constraints |
499 |
|
|
17.7 Utility Selection |
501 |
|
|
17.8 Furnaces |
503 |
|
|
17.9 Cogeneration (Combined Heat and Power Generation) |
506 |
|
|
17.10 Integration of Heat Pumps |
511 |
|
|
17.11 Number of Heat Exchange Units |
512 |
|
|
17.12 Heat Exchange Area Targets |
515 |
|
|
17.13 Sensitivity of Targets |
519 |
|
|
17.14 Capital and Total Cost Targets |
519 |
|
|
17.15 Heat Exchanger Network Targets – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
522 |
|
|
17.16 Exercises |
522 |
|
|
References |
525 |
|
|
Chapter 18: Heat Exchanger Networks II – Network Design |
133 |
|
|
18.1 The Pinch Design Method |
527 |
|
|
18.2 Design for Threshold Problems |
533 |
|
|
18.3 Stream Splitting |
533 |
|
|
18.4 Design for Multiple Pinches |
537 |
|
|
18.5 Remaining Problem Analysis |
542 |
|
|
18.6 Simulation of Heat Exchanger Networks |
544 |
|
|
18.7 Optimization of a Fixed Network Structure |
546 |
|
|
18.8 Automated Methods of Heat Exchanger Network Design |
549 |
|
|
18.9 Heat Exchanger Network Retrofit with a Fixed Network Structure |
551 |
|
|
18.10 Heat Exchanger Network Retrofit through Structural Changes |
556 |
|
|
18.11 Automated Methods of Heat Exchanger Network Retrofit |
562 |
|
|
18.12 Heat Exchanger Network Design – Summary |
564 |
|
|
18.13 Exercises |
565 |
|
|
References |
568 |
|
|
Chapter 19: Heat Exchanger Networks III – Stream Data |
569 |
|
|
19.1 Process Changes for Heat Integration |
569 |
|
|
19.2 The Trade–Offs Between Process Changes, Utility Selection, Energy Cost and Capital Cost???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
569 |
|
|
19.3 Data Extraction |
570 |
|
|
19.4 Heat Exchanger Network Stream Data – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
577 |
|
|
19.5 Exercises |
577 |
|
|
References |
579 |
|
|
Chapter 20: Heat Integration of Reactors |
581 |
|
|
20.1 The Heat Integration Characteristics of Reactors |
581 |
|
|
20.2 Appropriate Placement of Reactors |
583 |
|
|
20.3 Use of the Grand Composite Curve for Heat Integration of Reactors |
584 |
|
|
20.4 Evolving Reactor Design to Improve Heat Integration |
586 |
|
|
20.5 Heat Integration of Reactors – Summary |
587 |
|
|
20.6 Exercises |
587 |
|
|
Reference |
587 |
|
|
Chapter 21: Heat Integration of Distillation |
589 |
|
|
21.1 The Heat Integration Characteristics of Distillationƒ |
589 |
|
|
21.2 The Appropriate Placement of Distillation |
589 |
|
|
21.3 Use of the Grand Composite Curve for Heat Integration of Distillation |
590 |
|
|
21.4 Evolving the Design of Simple Distillation Columns to Improve Heat Integration |
590 |
|
|
21.5 Heat Pumping in Distillation |
593 |
|
|
21.6 Capital Cost Considerations for the Integration of Distillation |
593 |
|
|
21.7 Heat Integration Characteristics of Distillation Sequences |
594 |
|
|
21.8 Design of Heat Integrated Distillation Sequences |
597 |
|
|
21.9 Heat Integration of Distillation – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
598 |
|
|
21.10 Exercises |
598 |
|
|
References |
601 |
|
|
Chapter 22: Heat Integration of Evaporators and Dryers |
603 |
|
|
22.1 The Heat Integration Characteristics of Evaporators |
603 |
|
|
22.2 Appropriate Placement of Evaporators |
603 |
|
|
22.3 Evolving Evaporator Design to Improve Heat Integration |
603 |
|
|
22.4 The Heat Integration Characteristics of Dryers |
605 |
|
|
22.5 Evolving Dryer Design to Improve Heat Integration |
605 |
|
|
22.6 A Case Study |
607 |
|
|
22.7 Heat Integration of Evaporators and Dryers – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
607 |
|
|
22.8 Exercises |
608 |
|
|
References |
608 |
|
|
Chapter 23: Steam Systems and Cogeneration |
151 |
|
|
23.1 Boiler Feedwater Treatment |
611 |
|
|
23.2 Steam Boilers |
615 |
|
|
23.3 Gas Turbines |
621 |
|
|
23.4 Steam Turbines |
628 |
|
|
23.5 Steam Distribution |
635 |
|
|
23.6 Site Composite Curves |
638 |
|
|
23.7 Cogeneration Targets |
649 |
|
|
23.8 Power Generation and Machine Drives |
653 |
|
|
23.9 Utility Simulation |
657 |
|
|
23.10 Optimizing Steam Systems |
659 |
|
|
23.11 Steam Costs |
664 |
|
|
23.12 Steam Systems and Cogeneration – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
667 |
|
|
23.13 Exercises |
668 |
|
|
References |
671 |
|
|
Chapter 24: Cooling and Refrigeration Systems |
581 |
|
|
24.1 Cooling Systems |
673 |
|
|
24.2 Once-Through Water Cooling |
673 |
|
|
24.3 Recirculating Cooling Water Systems |
673 |
|
|
24.4 Air Coolers |
676 |
|
|
24.5 Refrigeration |
682 |
|
|
24.6 Choice of a Single-Component Refrigerant for Compression Refrigeration |
688 |
|
|
24.7 Targeting Refrigeration Power for Pure Component Compression Refrigeration |
691 |
|
|
24.8 Heat Integration of Pure Component Compression Refrigeration Processes |
695 |
|
|
24.9 Mixed Refrigerants for Compression Refrigeration |
699 |
|
|
24.10 Expanders |
703 |
|
|
24.11 Absorption Refrigeration |
707 |
|
|
24.12 Indirect Refrigeration |
708 |
|
|
24.13 Cooling Water and Refrigeration Systems – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
708 |
|
|
24.14 Exercises |
709 |
|
|
References |
711 |
|
|
Chapter 25: Environmental Design for Atmospheric Emissions |
713 |
|
|
25.1 Atmospheric Pollution |
713 |
|
|
25.2 Sources of Atmospheric Pollution |
714 |
|
|
25.3 Control of Solid Particulate Emissions to Atmosphere |
716 |
|
|
25.4 Control of VOC Emissions |
716 |
|
|
25.5 Control of Sulfur Emissions |
729 |
|
|
25.6 Control of Oxides of Nitrogen Emissions |
734 |
|
|
25.7 Control of Combustion Emissions |
737 |
|
|
25.8 Atmospheric Dispersion |
740 |
|
|
25.9 Environmental Design for Atmospheric Emissions – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
742 |
|
|
25.10 Exercises |
743 |
|
|
References |
746 |
|
|
Chapter 26: Water System Design |
747 |
|
|
26.1 Aqueous Contamination |
750 |
|
|
26.2 Primary Treatment Processes |
751 |
|
|
26.3 Biological Treatment Processes |
755 |
|
|
26.4 Tertiary Treatment Processes |
758 |
|
|
26.5 Water Use |
759 |
|
|
26.6 Targeting for Maximum Water Reuse for Single Contaminants for Operations with Fixed Mass Loads |
761 |
|
|
26.7 Design for Maximum Water Reuse for Single Contaminants for Operations with Fixed Mass Loads |
763 |
|
|
26.8 Targeting for Maximum Water Reuse for Single Contaminants for Operations with Fixed Flowrates |
773 |
|
|
26.9 Design for Maximum Water Reuse for Single Contaminants for Operations with Fixed Flowrates |
777 |
|
|
26.10 Targeting and Design for Maximum Water Reuse Based on Optimization of a Superstructure |
784 |
|
|
26.11 Process Changes for Reduced Water Consumption |
786 |
|
|
26.12 Targeting for Minimum Wastewater Treatment Flowrate for Single Contaminants |
787 |
|
|
26.13 Design for Minimum Wastewater Treatment Flowrate for Single Contaminants |
791 |
|
|
26.14 Regeneration of Wastewater |
793 |
|
|
26.15 Targeting and Design for Effluent Treatment and Regeneration Based on Optimization of a Superstructure |
798 |
|
|
26.16 Data Extraction |
799 |
|
|
26.17 Water System Design – Summary?????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
801 |
|
|
26.18 Exercises |
802 |
|
|
References |
805 |
|
|
Chapter 27: Environmental Sustainability in Chemical Production |
807 |
|
|
27.1 Life Cycle Assessment |
807 |
|
|
27.2 Efficient Use of Raw Materials Within Processes |
812 |
|
|
27.3 Efficient Use of Raw Materials Between Processes |
818 |
|
|
27.4 Exploitation of Renewable Raw Materials |
820 |
|
|
27.5 Efficient Use of Energy |
821 |
|
|
27.6 Integration of Waste Treatment and Energy Sytems |
831 |
|
|
27.7 Renewable Energy |
832 |
|
|
27.8 Efficient Use of Water |
833 |
|
|
27.9 Sustainability in Chemical Production – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
833 |
|
|
27.10 Exercises |
834 |
|
|
References |
835 |
|
|
Chapter 28: Process Safety |
837 |
|
|
28.1 Fire |
837 |
|
|
28.2 Explosion |
838 |
|
|
28.3 Toxic Release |
839 |
|
|
28.4 Hazard Identification |
839 |
|
|
28.5 The Hierarchy of Safety Management |
841 |
|
|
28.6 Inherently Safer Design |
841 |
|
|
28.7 Layers of Protection |
845 |
|
|
28.8 Hazard and Operability Studies |
848 |
|
|
28.9 Layer of Protection Analysis |
849 |
|
|
28.10 Process Safety – Summary???????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????????? |
849 |
|
|
28.11 Exercises |
850 |
|
|
References |
851 |
|
|
Appendix A: Physical Properties in Process Design |
853 |
|
|
A.1 Equations of State |
853 |
|
|
A.2 Phase Equilibrium for Single Components |
857 |
|
|
A.3 Fugacity and Phase Equilibrium |
857 |
|
|
A.4 Vapor–Liquid Equilibrium |
857 |
|
|
A.5 Vapor–Liquid Equilibrium Based on Activity Coefficient Models |
859 |
|
|
A.6 Group Contribution Methods for Vapor–Liquid Equilibrium |
861 |
|
|
A.7 Vapor–Liquid Equilibrium Based on Equations of State |
863 |
|
|
A.8 Calculation of Vapor–Liquid Equilibrium |
864 |
|
|
A.9 Liquid–Liquid Equilibrium |
867 |
|
|
A.10 Liquid–Liquid Equilibrium Activity Coefficient Models |
868 |
|
|
A.11 Calculation of Liquid–Liquid Equilibrium |
868 |
|
|
A.12 Choice of Method for Equilibrium Calculations |
870 |
|
|
A.13 Calculation of Enthalpy |
872 |
|
|
A.14 Calculation of Entropy |
873 |
|
|
A.15 Other Physical Properties |
874 |
|
|
A.16 Physical Properties in Process Design – Summary |
876 |
|
|
A.17 Exercises |
877 |
|
|
References |
878 |
|
|
Appendix B: Materials of Construction |
581 |
|
|
B.1 Mechanical Properties |
879 |
|
|
B.2 Corrosion |
880 |
|
|
B.3 Corrosion Allowance |
881 |
|
|
B.4 Commonly used Materials of Construction |
881 |
|
|
B.5 Criteria for Selection |
885 |
|
|
B.6 Materials of Construction – Summary |
886 |
|
|
References |
886 |
|
|
Appendix C: Annualization of Capital Cost |
887 |
|
|
Reference |
887 |
|
|
Appendix D: The Maximum Thermal Effectiveness for 1–2 Shell-and-Tube Heat Exchangers |
27 |
|
|
References |
889 |
|
|
Appendix E: Expression for the Minimum Number of 1–2 Shell-and-Tube Heat Exchangers for a Given Unit |
891 |
|
|
References |
892 |
|
|
Appendix F: Heat Transfer Coefficient and Pressure Drop in Shell-and-Tube Heat Exchangers |
893 |
|
|
F.1 Heat Transfer and Pressure Drop Correlations for the Tube Side |
893 |
|
|
F.2 Heat Transfer and Pressure Drop Correlations for the Shell Side |
895 |
|
|
References |
899 |
|
|
Appendix G: Gas Compression Theory |
837 |
|
|
G.1 Modeling Reciprocating Compressors |
901 |
|
|
G.2 Modeling Dynamic Compressors |
903 |
|
|
G.3 Staged Compression |
903 |
|
|
References |
905 |
|
|
Appendix H: Algorithm for the Heat Exchanger Network Area Target |
907 |
|
|
Index |
211 |
|
|
EULA |
923 |
|