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Preface |
6 |
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Contents |
8 |
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Modern Physics of Ferroelectrics: Essential Background |
14 |
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1 Introduction |
14 |
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2 Switching and Hysteresis Loops |
15 |
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3 Crystallographic Signature of Ferroelectricity |
19 |
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4 Materials |
21 |
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5 Applications of Ferroelectric Materials |
33 |
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6 Note from the Editors |
36 |
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References |
36 |
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Index |
42 |
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Theory of Polarization: A Modern Approach |
44 |
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1 Why is a Modern Approach Needed? |
44 |
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2 Polarization as an Adiabatic Flow of Current |
49 |
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3 Formal Description of the Berry-Phase Theory |
54 |
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4 Implications for Ferroelectrics |
65 |
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5 Further Theoretical Developments |
70 |
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6 Summary |
77 |
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References |
78 |
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Index |
80 |
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A Landau Primer for Ferroelectrics |
82 |
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1 Introduction |
82 |
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2 Landau–Devonshire Theory |
87 |
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3 Landau–Ginzburg Theory |
97 |
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4 Reduced Size and Other Boundary Effects |
105 |
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5 Summary and (Some) Open Questions |
117 |
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References |
119 |
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Index |
128 |
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First-Principles Studies of Ferroelectric Oxides |
129 |
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1 Introduction |
129 |
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2 First-Principles Methods |
130 |
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3 Results for Perovskite Oxide Compounds |
135 |
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4 Results for Other Ferroelectric Oxide Compounds |
155 |
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5 Results for Solid Solutions |
158 |
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6 Results for Defects |
162 |
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7 Results for Surfaces, Thin Films, Superlattices, Nanowires and Nanoparticles |
164 |
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8 Challenges and Prospects |
166 |
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References |
168 |
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Index |
185 |
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Analogies and Differences between Ferroelectrics and Ferromagnets |
188 |
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1 Fundamentals |
190 |
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2 Applications |
207 |
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3 Multiferroics |
211 |
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4 Outlook |
223 |
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References |
224 |
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Index |
229 |
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Growth and Novel Applications of Epitaxial Oxide Thin Films |
231 |
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1 Introduction |
231 |
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2 Thin-Film Growth of Complex Oxides |
233 |
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3 Substrates |
269 |
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4 Applications of Epitaxial Oxide Thin Films |
281 |
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References |
302 |
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Index |
316 |
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Ferroelectric Size Effects |
317 |
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1 Size Effects in Ferroelectrics |
317 |
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2 Size Effects in the Ginzburg–Landau–Devonshire Theory |
318 |
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3 Extrinsic Size Effects |
319 |
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4 Effect of Screening |
320 |
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5 Superlattices |
336 |
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6 Other Geometries |
338 |
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References |
342 |
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Index |
349 |
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Nanoscale Studies of Domain Walls in Epitaxial Ferroelectric Thin Films |
350 |
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1 Introduction |
350 |
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2 Ferroelectric Domain Walls as Elastic Disordered Systems |
351 |
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3 Static and Dynamic Behavior of Elastic Disordered Systems |
352 |
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4 Experimental Observation of Domain-Wall Creep |
355 |
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5 Domain-Wall Creep in a Commensurate Potential |
358 |
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6 Domain-Wall Creep in a Random Potential |
362 |
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7 Experimental Observation of Domain-Wall Roughness |
365 |
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8 Domain Walls in the Presence of Random- Bond Disorder and Dipolar Interactions |
368 |
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9 Recent Studies of Ferroelectric Domain-Wall Dynamics |
369 |
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10 Conclusions |
370 |
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References |
371 |
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Index |
373 |
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APPENDIX A – Landau Free- Energy Coefficients |
374 |
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Appendix B – Material– Substrate Combinations Tables |
383 |
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