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Aerosol Technology: Properties, Behavior, and Measurement of Airborne Particles, Second Edition |
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CONTENTS |
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Preface to the First Edition |
13 |
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Preface to the Second Edition |
15 |
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List of Principal Symbols |
17 |
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1 Introduction |
23 |
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1.1 Definitions |
25 |
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1.2 Particle Size, Shape, and Density |
30 |
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1.3 Aerosol Concentration |
32 |
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Problems |
34 |
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References |
35 |
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2 Properties of Gases |
37 |
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2.1 Kinetic Theory of Gases |
37 |
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2.2 Molecular Velocity |
40 |
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2.3 Mean Free Path |
43 |
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2.4 Other Properties |
45 |
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2.5 Reynolds Number |
49 |
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2.6 Measurement of Velocity, Flow Rate, and Pressure |
53 |
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Problems |
61 |
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References |
63 |
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3 Uniform Particle Motion |
64 |
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3.1 Newton's Resistance Law |
64 |
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3.2 Stokes's Law |
66 |
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3.3 Settling Velocity and Mechanical Mobility |
68 |
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3.4 Slip Correction Factor |
70 |
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3.5 Nonspherical Particles |
73 |
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3.6 Aerodynamic Diameter |
75 |
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3.7 Settling at High Reynolds Numbers |
77 |
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3.8 Stirred Settling |
84 |
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3.9 Instruments That Rely on Settling Velocity |
87 |
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3.10 Appendix: Derivation of Stokes's Law |
89 |
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Problems |
92 |
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References |
95 |
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4 Particle Size Statistics |
97 |
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4.1 Properties of Size Distributions |
97 |
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4.2 Moment Averages |
104 |
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4.3 Moment Distributions |
106 |
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4.4 The Lognormal Distribution |
112 |
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4.5 Log-Probability Graphs |
116 |
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4.6 The Hatch–Choate Conversion Equations |
119 |
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4.7 Statistical Accuracy |
122 |
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4.8 Appendix 1: Distributions Applied to Particle Size |
126 |
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4.9 Appendix 2: Theoretical Basis for Aerosol Particle Size Distributions |
127 |
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4.10 Appendix 3: Derivation of the Hatch–Choate Equations |
127 |
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Problems |
130 |
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References |
132 |
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5 Straight-Line Acceleration and Curvilinear Particle Motion |
133 |
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5.1 Relaxation Time |
133 |
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5.2 Straight-Line Particle Acceleration |
134 |
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5.3 Stopping Distance |
139 |
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5.4 Curvilinear Motion and Stokes Number |
141 |
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5.5 Inertial Impaction |
143 |
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5.6 Cascade Impactors |
150 |
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5.7 Virtual Impactors |
156 |
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5.8 Time-of-Flight Instruments |
158 |
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Problems |
160 |
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References |
162 |
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6 Adhesion of Particles |
163 |
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6.1 Adhesive Forces |
163 |
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6.2 Detachment of Particles |
166 |
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6.3 Resuspension |
167 |
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6.4 Particle Bounce |
168 |
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Problems |
169 |
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References |
170 |
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7 Brownian Motion and Diffusion |
172 |
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7.1 Diffusion Coefficient |
172 |
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7.2 Particle Mean Free Path |
176 |
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7.3 Brownian Displacement |
178 |
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7.4 Deposition by Diffusion |
182 |
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7.5 Diffusion Batteries |
187 |
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Problems |
190 |
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References |
191 |
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8 Thermal and Radiometric Forces |
193 |
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8.1 Thermophoresis |
193 |
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8.2 Thermal Precipitators |
198 |
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8.3 Radiometric and Concentration Gradiant Forces |
200 |
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Problems |
202 |
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References |
202 |
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9 Filtration |
204 |
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9.1 Macroscopic Properties of Filters |
204 |
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9.2 Single-Fiber Efficiency |
212 |
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9.3 Deposition Mechanisms |
213 |
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9.4 Filter Efficiency |
218 |
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9.5 Pressure Drop |
222 |
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9.6 Membrane Filters |
224 |
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Problems |
226 |
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References |
226 |
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10 Sampling and Measurement of Concentration |
228 |
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10.1 Isokinetic Sampling |
228 |
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10.2 Sampling from Still Air |
235 |
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10.3 Transport Losses |
238 |
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10.4 Measurement of Mass Concentration |
239 |
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10.5 Direct-Reading Instruments |
244 |
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10.6 Measurement of Number Concentration |
247 |
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10.7 Sampling Pumps |
250 |
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Problems |
252 |
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References |
253 |
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11 Respiratory Deposition |
255 |
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11.1 The Respiratory System |
255 |
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11.2 Deposition |
257 |
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11.3 Deposition Models |
264 |
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11.4 Inhalability of Particles |
267 |
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11.5 Respirable and Other Size-Selective Sampling |
271 |
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Problems |
279 |
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References |
280 |
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12 Coagulation |
282 |
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12.1 Simple Monodisperse Coagulation |
282 |
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12.2 Polydisperse Coagulation |
290 |
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12.3 Kinematic Coagulation |
294 |
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Problems |
298 |
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References |
299 |
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13 Condensation and Evaporation |
300 |
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13.1 Definitions |
300 |
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13.2 Kelvin Effect |
303 |
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13.3 Homogeneous Nucleation |
305 |
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13.4 Growth by Condensation |
307 |
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13.5 Nucleated Condensation |
310 |
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13.6 Condensation Nuclei Counters |
314 |
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13.7 Evaporation |
316 |
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Problems |
323 |
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References |
324 |
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14 Atmospheric Aerosols |
326 |
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14.1 Natural Background Aerosol |
326 |
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14.2 Urban Aerosol |
329 |
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14.3 Global Effects |
334 |
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Problems |
336 |
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References |
337 |
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15 Electrical Properties |
338 |
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15.1 Units |
338 |
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15.2 Electric Fields |
340 |
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15.3 Electrical Mobility |
342 |
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15.4 Charging Mechanisms |
345 |
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15.5 Corona Discharge |
353 |
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15.6 Charge Limits |
355 |
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15.7 Equilibrium Charge Distribution |
357 |
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15.8 Electrostatic Precipitators |
360 |
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15.9 Electrical Measurement of Aerosols |
363 |
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Problems |
368 |
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References |
369 |
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16 Optical Properties |
371 |
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16.1 Definitions |
372 |
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16.2 Extinction |
374 |
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16.3 Scattering |
380 |
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16.4 Visibility |
386 |
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16.5 Optical Measurement of Aerosols |
392 |
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Problems |
398 |
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References |
399 |
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17 Bulk Motion of Aerosols |
401 |
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Problems |
407 |
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References |
407 |
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18 Dust Explosions |
408 |
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Problems |
414 |
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References |
414 |
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19 Bioaerosols |
416 |
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19.1 Characteristics |
416 |
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19.2 Sampling |
418 |
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Problems |
422 |
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References |
422 |
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20 Microscopic Measurement of Particle Size |
424 |
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20.1 Equivalent Sizes of Irregular Particles |
424 |
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20.2 Fractal Dimension of Particles |
430 |
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20.3 Optical Microscopy |
435 |
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20.4 Electron Microscopy |
438 |
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20.5 Asbestos Counting |
444 |
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20.6 Automatic Sizing Methods |
446 |
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Problems |
447 |
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References |
448 |
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21 Production of Test Aerosols |
450 |
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21.1 Atomization of Liquids |
450 |
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21.2 Atomization of Monodisperse Particles in Liquid Suspensions |
456 |
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21.3 Dispersion of Powders |
460 |
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21.4 Condensation Methods |
465 |
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Problems |
467 |
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References |
468 |
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Appendices |
469 |
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A1. Useful Constants and Conversions Factors |
469 |
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A2. Some Basic Physical Laws |
471 |
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A3. Relative Density of Common Aerosol Materials |
473 |
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A4. Standard Sieve Sizes |
473 |
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A5. Properties of Gases and Vapors at 293 K [20°C] and 101 kPa [1 atm] |
474 |
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A6. Viscosity and Density of Air versus Temperature |
474 |
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A7. Pressure, Temperature, Density, and Mean Free Path of Air versus Altitude |
475 |
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A8. Properties of Water Vapor |
477 |
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A9. Properties of Water |
477 |
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A10. Particle Size Range of Aerosol Properties and Measurement Instruments |
478 |
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A11. Properties of Airborne Particles at Standard Conditions |
480 |
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A12. Slip Correction Factor for Standard and Nonstandard Conditions |
482 |
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A13. Properties of Selected Low-Vapor-Pressure Liquids |
483 |
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A14. Reference Values for Atmospheric Properties at Sea Level and 293 K [20°C] |
484 |
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A15. Greek Symbols Used in This Book |
486 |
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A16. SI Prefixes |
486 |
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Index |
487 |
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